Petrological evidence for shock‐induced high‐P metamorphism in a gabbro          下载免费PDF全文

J.‐J. Yang  H.‐R. Zhang  A.‐P. Chen  M.‐X. Huang 《Journal of Metamorphic Geology》2017,35(2):121-140

Microlites (minute spherulitic, dendritic, skeletal, acicular and poikilitic crystals) diagnostic of crystallization in quenched melt or glass in fault rocks have been used to infer fossil earthquakes. High‐P microlites and crystallites are described here in a variably eclogitized gabbro, the wallrock to the coesite‐bearing eclogite breccia at Yangkou in the Chinese Su‐Lu high‐P metamorphic belt. The studied hand specimens are free of discernible shear deformation, although microfractures are not uncommon under the microscope. In the least eclogitized gabbro, the metagabbro, stellate growths of high‐P minerals on the relict igneous minerals are common. Dendritic garnet crystals (<1?5 μm) grew around rutile and/or phengite replacing ilmenite and biotite, respectively. Skeletal garnet also rims broken flakes of igneous biotite and mechanically twinned augite. Radial intergrowths of omphacite and quartz developed around relict igneous orthopyroxene and are rimmed by skeletal or poikilitic garnet where a Ti‐bearing mineral relict is present. Acicular epidote, kyanite and phengite crystallites are randomly distributed in a matrix of Na‐rich plagioclase, forming the pseudomorphs after igneous plagioclase. In the more eclogitized gabbro, the coronitic eclogite located closer to the eclogite breccia, all the igneous minerals broke down into high‐P assemblages. Thick coronas of poikilitic garnet grew between the pseudomorphs after igneous plagioclase and ferromagnesian minerals. The igneous plagioclase is replaced by omphacite crystallites, with minor amounts of phengite and kyanite. Thermodynamic modelling of the plagioclase pseudomorphs shows an increase in P–T in the wallrock from the metagabbro to the coronitic eclogite, and the P–T variation is unrelated to H₂O content. The fluid‐poor pressure overstepping scenario is unsupported both by phase diagram modelling and by whole‐rock chemical data, which show that the various types of eclogitized gabbro are all fairly dry. A large pressure difference of >2 GPa between the metagabbro and the coesite‐bearing eclogites ~20 m apart cannot be explained by the subduction hypothesis because this would require a depth difference of >60 km. The microlites and crystallites are evidence for dynamic crystallization due to rapid cooling because constitutional supercooling was unlikely for the plagioclase pseudomorphs. The lack of annealing of the broken biotite and augite overgrown by strain free skeletal garnet is consistent with a transient high‐P–T event at a low ambient temperature (<300 °C), probably in the crust. Therefore, the eclogitization of the wallrock to the eclogite breccia was also coseismic, as proposed earlier for the eclogite facies fault rocks. The outcrop‐scale P–T variation and the transient nature of the high‐P–T event are inconsistent with the other existing tectonic models for high‐P metamorphism. The fact that the less refractory but denser biotite is largely preserved while the more refractory but less dense plagioclase broke down completely into high‐P microlite assemblages in the metagabbro indicates a significant rise in pressure rather than temperature. Given that the metamorphic temperatures are far below the melting temperatures of most of the gabbroic minerals under fluid‐absent conditions, stress‐induced amorphization appears to be the more likely mechanism of the coseismic high‐P metamorphism.  相似文献   

Metamorphic condition of a regional metamorphic complex in the Omuta district in northern Kyushu,southwest Japan          下载免费PDF全文

Takeshi Ikeda  Kazuhiro Miyazaki  Hirohisa Matsuura 《Island Arc》2017,26(5)

A high‐temperature (T) metamorphic complex occurs in the Omuta district, northern Kyushu, Japan. Three metamorphic zones are defined based on pelitic mineral assemblage, i.e. chlorite–biotite zone, muscovite–andalusite zone and sillimanite–K‐feldspar zone with ascending metamorphic grade from north to south. Two isograds trend approximately east–west, which is oblique to the boundary between the metamorphic complex and the Tamana Granodiorite located on the southeast. The metamorphic condition of two pelitic rocks that occur in the muscovite–andalusite zone and sillimanite–K‐feldspar zone are estimated as 510 ±30 °C, 300 ±60 MPa and 720 ±30 °C, 620 ±60 MPa, respectively. Thermodynamic consideration reveals that use of the same geothermobarometer enables precise determination of the difference in pressure between the samples as 320 ±10 MPa. This indicates that the pelitic samples were metamorphosed at different depth by 11–12 km that is significantly larger than the geographic distance of 6.8 km between the sample localities. This also suggests that crustal thinning took place after the high‐T metamorphism. The high‐T metamorphic complex is, therefore, not of static contact metamorphism but of dynamic regional metamorphism. The present result combined with petrological and chronological similarities implies that this complex suffered the regional Ryoke metamorphism.  相似文献   

P–T evolution of kyanite eclogite from the Pirin Mountains (SW Bulgaria): implications for the Rhodope UHP Metamorphic Complex     

M. JANÁK  N. FROITZHEIM  N. GEORGIEV  T. J. NAGEL  S. SAROV 《Journal of Metamorphic Geology》2011,29(3):317-332

A new occurrence of kyanite eclogite in the Pirin Mountains of southwestern Bulgaria within the rocks belonging to the Obidim Unit of the Rhodope Metamorphic Complex is presented. This eclogite provides important information about the peak–pressure conditions despite strong thermal overprint at low pressure. Textural relationships, phase equilibrium modelling and conventional geothermobarometry were used to constrain the metamorphic evolution. Garnet porphyroblasts with inclusions of omphacite (up to 43 mol.% Jd), phengite (up to 3.5 Si p.f.u.), kyanite, polycrystalline quartz, pargasitic amphibole, zoisite and rutile in the Mg‐rich cores (X_Mg = 0.44–0.46) record a prograde increase in P–T conditions from ～2.5 GPa and 650 °C to ～3 GPa and 700–750 °C. Maximum pressure values fall within the stability field of coesite. During exhumation, the peak–pressure assemblage garnet + omphacite + phengite + kyanite was variably overprinted by a lower pressure one forming symplectitic textures, such as diopside + plagioclase after omphacite and biotite + plagioclase after phengite. The development of spinel (X_Mg = 0.4–0.45) + corundum + anorthite assemblage in the kyanite‐bearing domains at ～1.1 GPa and 800–850 °C suggests a thermal overprint in the high‐pressure granulite facies stability field. This thermal event was followed by cooling at ～0.8 GPa under amphibolite facies conditions; retrograde kelyphite texture involving plagioclase and amphibole was developed around garnet. Our results add to the already existing evidence for ultra high pressure (UHP) metamorphism in the Upper Allochthon of the Rhodope Metamorphic Complex as in the Kimi Unit and show that it is more widespread than previously known. Published age data and field structural relations suggest that the Obidim Unit represents Variscan continental crust involved into the Alpine nappe edifice of the Rhodopes and that eclogite facies metamorphism was Palaeozoic, in contrast to the Kimi Unit where age determinations suggest a Jurassic or Cretaceous age for UHP metamorphism. This implies that UHP metamorphism in the Upper Allochthon of the Rhodopes may have occurred twice, during Alpine and pre‐Alpine orogenic events, and that two independent HP/UHP provinces of different age overlap in this area.  相似文献   

Geochronological and petrological constraints from the evolution in the Saxon Granulite Massif,Germany, on the Variscan continental collision orogeny     

Jochen Rtzler  Martin J. Timmerman 《Journal of Metamorphic Geology》2021,39(1):3-38

Controversy over the plate tectonic affinity and evolution of the Saxon granulites in a two‐ or multi‐plate setting during inter‐ or intracontinental collision makes the Saxon Granulite Massif a key area for the understanding of the Palaeozoic Variscan orogeny. The massif is a large dome structure in which tectonic slivers of metapelite and metaophiolite units occur along a shear zone separating a diapir‐like body of high‐P granulite below from low‐P metasedimentary rocks above. Each of the upper structural units records a different metamorphic evolution until its assembly with the exhuming granulite body. New age and petrologic data suggest that the metaophiolites developed from early Cambrian protoliths during high‐P amphibolite facies metamorphism in the mid‐ to late‐Devonian and thermal overprinting by the exhuming hot granulite body in the early Carboniferous. A correlation of new Ar–Ar biotite ages with published P–T–t data for the granulites implies that exhumation and cooling of the granulite body occurred at average rates of ~8 mm/year and ~80°C/Ma, with a drop in exhumation rate from ~20 to ~2.5 mm/year and a slight rise in cooling rate between early and late stages of exhumation. A time lag of c. 2 Ma between cooling through the closure temperatures for argon diffusion in hornblende and biotite indicates a cooling rate of 90°C/Ma when all units had assembled into the massif. A two‐plate model of the Variscan orogeny in which the above evolution is related to a short‐lived intra‐Gondwana subduction zone conflicts with the oceanic affinity of the metaophiolites and the timescale of c. 50 Ma for the metamorphism. Alternative models focusing on the internal Variscan belt assume distinctly different material paths through the lower or upper crust for strikingly similar granulite massifs. An earlier proposed model of bilateral subduction below the internal Variscan belt may solve this problem.  相似文献   

O₂-O₂云反演算法及其在TROPOMI上的应用     

张文强  刘诚  郝楠  Gimeno Garcia Sebastian  邢成志  张成歆  苏文静  刘建国 《遥感学报》2020,24(11):1363-1378

利用遥感技术对大气环境污染进行监测时，云是影响痕量气体反演精度的重要因素，因此在痕量气体反演中需要对云的影响进行校正，通常使用的云参数主要是有效云量和云压。本文基于O₂-O₂ 477 nm吸收波段构建了O₂-O₂云反演算法：首先，根据有效云量和云高与连续反射率和O₂-O₂斜柱浓度之间的对应关系，结合假定的云模型利用VLIDORT辐射传输模型建立关于有效云量和云压的查找表；然后，通过差分吸收光谱技术拟合卫星载荷观测的大气层顶辐射，获得O₂-O₂斜柱浓度并计算连续反射率；最后，结合辅助数据，根据查找表进行插值反演获得有效云量和云压。通过将算法应用到OMI观测数据，将反演结果与OMCLDO2产品进行对比验证，有效云量和云压空间分布一致，相关系数R均超过0.97；并还将该算法应用于下一代大气成分监测仪器TROPOMI，与FRESCO+产品对比，有效云量和云压空间分布基本一致，当地表类型为海洋时，有效云量相关系数R大于0.97，云压相关系数R大于0.94，云压反演结果存在一定的区别；通过将O₂-O₂云反演算法和FRESCO+云压反演结果与CALIOP Cloud Layer产品进行对比，结果表明，在低云情况下，O₂-O₂云反演算法线性回归方程斜率为0.782，截距为198.0 hPa，相关系数R为0.850，算法表现优于FRESCO+。而在高云情况下，FRESCO+反演结果更接近CALIOP云压结果。在OMI和TROPOMI上的应用表明O₂-O₂云反演算法在大气云反演中具有较高的准确性和可行性，可以为大气痕量气体反演的校正提供云参数，并为中国同类型卫星载荷的云反演算法提供算法参考。  相似文献   

Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction          下载免费PDF全文

M. Janák  N. Froitzheim  K. Yoshida  V. Sasinková  M. Nosko  T. Kobayashi  T. Hirajima  M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.  相似文献   

Grain‐scale pressure variations and chemical equilibrium in high‐grade metamorphic rocks     

L. Tajčmanová  Y. Podladchikov  R. Powell  E. Moulas  J.C. Vrijmoed  J.A.D. Connolly 《Journal of Metamorphic Geology》2014,32(2):195-207

In the classical view of metamorphic microstructures, fast viscous relaxation (and so constant pressure) is assumed, with diffusion being the limiting factor in equilibration. This contribution is focused on the only other possible scenario – fast diffusion and slow viscous relaxation – and brings an alternative interpretation of microstructures typical of high‐grade metamorphic rocks. In contrast to the pressure vessel mechanical model applied to pressure variation associated with coesite inclusions in various host minerals, a multi‐anvil mechanical model is proposed in which strong single crystals and weak grain boundaries can maintain pressure variation at geological time‐scales in a polycrystalline material. In such a mechanical context, exsolution lamellae in feldspar are used to show that feldspar can sustain large differential stresses (>10 kbar) at geological time‐scales. Furthermore, it is argued that the existence of grain‐scale pressure gradients combined with diffusional equilibrium may explain chemical zoning preserved in reaction rims. Assuming zero net flux across the microstructure, an equilibrium thermodynamic method is introduced for inferring pressure variation corresponding to the chemical zoning. This new barometric method is applied to plagioclase rims around kyanite in felsic granulite (Bohemian Massif, Czech Republic), yielding a grain‐scale pressure variation of 8 kbar. In this approach, kinetic factors are not invoked to account for mineral composition zoning preserved in rocks metamorphosed at high grade.  相似文献   

Tectonometamorphic evolution of the Atbashi high‐P units (Kyrgyz CAOB,Tien Shan): Implications for the closure of the Turkestan Ocean and continental subduction–exhumation of the South Kazakh continental margin          下载免费PDF全文

Chloé Loury  Yann Rolland  Stéphane Guillot  Pierre Lanari  Clément Ganino  Raphael Melis  Anthony Jourdon  Carole Petit  Olivier Beyssac  Sylvain Gallet  Patrick Monié 《Journal of Metamorphic Geology》2018,36(8):959-985

The South Tien Shan (STS) belt results from the last collision event in the western Central Asian Orogenic Belt (CAOB). Understanding its formation is of prime importance in the general framework of the CAOB. The Atbashi Range preserves high‐P (HP) rocks along the STS suture, but still, its global metamorphic evolution remains poorly constrained. Several HP units have been identified: (a) a HP tectonic mélange including boudins of mafic eclogites in a sedimentary matrix, (b) a large (>100 km long) high‐P metasedimentary unit (HPMU) and (c) a lower blueschist facies accretionary prism. Raman Spectroscopy on carbonaceous material combined with phengite and chlorite multiequilibria and isochemical phase diagram modelling indicates that the HPMU recorded homogeneous P–T conditions of 23–25 kbar and 560–570°C along the whole unit. ⁴⁰Ar/³⁹Ar dating on phengite from the HPMU ranges between 328 and 319 Ma at regional scale. These ages are interpreted as (re‐) crystallization ages of phengite during T_max conditions at a pressure range of 20–25 kbar. Thermobarometry on samples from the HP tectonic mélange provides similar metamorphic peak conditions. Thermobarometry on the blueschist to lower greenschist facies accretionary prism indicates that it underwent P–T conditions of 5–6 kbar and 290–340°C, highlighting a 17–20 kbar pressure gap between the HPMU‐tectonic mélange units and the accretionary prism. Comparison with available geochronological data suggests a very short time span between the prograde path (340 Ma), HP metamorphic peak (330 Ma), the T_max (328–319 Ma) and the final exhumation of the HPMU (303–295 Ma). Extrusion of the HPMU, accommodated by a basal thrust and an upper detachment, was driven by buoyant forces from 70–75 km up to 60 km depth, which directly followed continental subduction and detachment of the HPMU. At crustal depths, extrusion was controlled by collisional tectonics up to shallow levels. Lithological homogeneity of the HPMU and its continental‐derived character from the North Tien Shan suggest this unit corresponds to the hyper‐extended continental margin of the Kazakh continent, subducted southward below the north continental active margin of the Tarim craton. Integration of the available geological data allows us to propose a general geodynamic scenario for Tien Shan during the Carboniferous with a combination of (a) N‐dipping subduction below the Kazakh margin of Middle Tien Shan until 390–340 Ma and (b) S‐dipping subduction of remaining Turkestan marginal basins between 340 and 320 Ma.  相似文献   

盾构辅助常压开仓技术在南宁地铁隧道中的应用          下载免费PDF全文

曲兆雷 《探矿工程》2020,47(2):88-93

盾构开仓是盾构隧道施工中难以避免的一道工序，结合南宁地铁四号线总部基地站-飞龙路站区间隧道的盾构开仓实践经验，介绍了素桩加降水这一辅助常压开仓技术在南宁地铁隧道中成功应用的实例。在介绍工程应用背景的基础上，详细叙述了辅助开仓方法中素桩及降水施工的技术要点，可为南宁地区盾构开仓方案选择提供指导，也可为类似条件下盾构开仓方案的选择提供借鉴。  相似文献   

湖南寒婆坳矿区热变质煤结构演化及其矿物学特征响应   总被引：1，自引：0，他引：1  

李焕同  王楠  朱志蓉  石媛  莫佳峰  张卫国  方世跃 《地质学报》2020,94(11):3503-3514

采用X射线荧光光谱(XRF)、差热分析(DTA)、扫描电子显微镜(SEM)、高分辨透射电镜(HRTEM)、X射线衍射(XRD)和拉曼光谱(Raman)等表征手段对湖南寒婆坳矿区热变质煤的化学组分、物理性质、结构演化与其矿物学特征响应进行了研究。结果表明：岩浆侵入体的热力及构造应力作用促进煤化程度升高逐渐转变为隐晶质石墨，氢、碳原子数目比(H/C)逐渐降低，矿物主要为伊利石、绿泥石、叶蜡石、石英及黄铁矿等；随变质程度增加，真密度升高，孔隙度与电阻率降低；在400℃之后，失重曲线下降缓慢且斜率变小，显示深度裂解与脱落较少。 d 002、 L a、 L c的演化趋势呈非线性变化，显示煤有机大分子结构向石墨化演化的过程中呈现“跃变”；隐晶质石墨样品的晶体结构主要为2H型石墨结构，不同程度地含有3R多型，石墨化度为0. 47~0. 84，石墨晶体轴长 a 为0. 2469~0. 2471 nm， c 为0. 6738~0. 6762 nm，晶胞体积 V 为0. 03562~0. 03570 nm3，显示靠近岩体晶胞体积减小；随着变质程度升高， L a、 L c迅速增加，堆叠层数急剧增大，煤内部空间结构趋于有序化，拉曼参数 A D1、 P (G- D1)逐渐降低。  相似文献